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Endrin ketone

Item number680868
CAS53494-70-5
FormulaC12H8Cl6O
Molecular weight380,91 g/mol
Quantity 1x25mg
Storage conditions20 °C
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Endrin ketone

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate May 21, 2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Endrin ketone
Catalog No.:680868
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008
Acute toxicity - Oral Category 2 - (H300)
Acute toxicity - Dermal Category 3 - (H311)
Acute toxicity - Inhalation (Dusts/Mists) Category 3 - (H331)
Acute aquatic toxicity Category 1 - (H400)
Chronic aquatic toxicity Category 1 - (H410)
Label elements
PictogramGHS06 skull
skull
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2. Label elements
Signal word
Danger
Hazard statements
H300 - Fatal if swallowed
H311 - Toxic in contact with skin
H331 - Toxic if inhaled
H410 - Very toxic to aquatic life with long lasting effects
Precautionary Statements - EU (§28, 1272/2008)
P273 - Avoid release to the environment
P280 - Wear protective gloves and protective clothing
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
2.3. Other hazards
No information available.
This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Chemical name: Endrin Ketone
EC No: 625-032-8
Classification
according to
Regulation (EC) No.
1272/2008 [CLP]
Acute Tox. 2 (H300)
Acute Tox. 3 (H311)
Acute Tox. 3 (H331)
Aquatic Acute 1 (H400)
Aquatic Chronic 1 (H410)
Acute Toxicity Estimate
If LD50/LC50 data is not available or does not correspond to the classification category, then the appropriate conversion
value from CLP Annex I, Table 3.1.2, is used to calculate the acute toxicity estimate (ATEmix) for classifying a mixture
based on its components
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

FormulaC12H8Cl6O
Molecular Weight (g/mol)380.91
CAS-No.53494-70-5
FIRST AID MEASURES4.1. Description of first aid measures
General advice Immediate medical attention is required. Show this safety data sheet to the doctor in
attendance.
Inhalation If breathing has stopped, give artificial respiration. Get medical attention immediately.
Remove to fresh air. Do not breathe dust. Do not use mouth-to-mouth method if victim
ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device. If breathing is
difficult, (trained personnel should) give oxygen.
Eye contact Get immediate medical advice/attention. Rinse immediately with plenty of water, also under
the eyelids, for at least 15 minutes. Keep eye wide open while rinsing.
Skin contact Get immediate medical advice/attention. Wash off immediately with soap and plenty of
water while removing all contaminated clothes and shoes.
Ingestion Get immediate medical advice/attention. Do NOT induce vomiting. Rinse mouth. Never give
anything by mouth to an unconscious person.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination. Do not breathe dust. Do not use
mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration
with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
medical device. Use personal protective equipment as required. See section 8 for more
information.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms Coughing and/ or wheezing. Difficulty in breathing.
4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors Treat symptomatically.

FIRE-FIGHTING MEASURES5.1. Extinguishing media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the
chemical
No information available.
5.3. Advice for firefighters
Special protective equipment and
precautions for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout
gear. Use personal protection equipment.
ACCIDENTAL RELEASE MEASURES6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required. Evacuate personnel to safe areas. Avoid generation of
dust. Do not breathe dust. Keep people away from and upwind of spill/leak.
Other information Refer to protective measures listed in Sections 7 and 8.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental precautions
Environmental precautions Prevent further leakage or spillage if safe to do so.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information.
HANDLING AND STORAGE7.1. Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Take off contaminated clothing and wash it before reuse. Do not
breathe dust. Avoid generation of dust. In case of insufficient ventilation, wear suitable
respiratory equipment. Handle product only in closed system or provide appropriate exhaust
ventilation. Do not eat, drink or smoke when using this product.
General hygiene considerations Wash hands before breaks and immediately after handling the product. Remove and wash
contaminated clothing and gloves, including the inside, before re-use. Regular cleaning of
equipment, work area and clothing is recommended. Avoid contact with skin, eyes or
clothing. Do not eat, drink or smoke when using this product. Wash hands before breaks
and after work. Wear suitable gloves and eye/face protection. Do not breathe dust. Take off
contaminated clothing and wash it before reuse. Contaminated work clothing should not be
allowed out of the workplace.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Store locked up. Keep containers tightly closed in a dry, cool and well-ventilated place.
Keep out of the reach of children. Please refer to the manufacturers certificate for specific
storage and transport temperature conditions. Store only in the original receptacle unless
other advice is given on the CoA.
7.3. Specific end use(s)
Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1. Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits
This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific
regulatory bodies
Derived No Effect Level (DNEL) No information available.
Predicted No Effect Concentration
(PNEC)
No information available.
8.2. Exposure controls
Personal protective equipment
Eye/face protection Avoid contact with eyes. Wear safety glasses with side shields (or goggles).
Hand protection Wear suitable gloves. Impervious gloves. The protective gloves to be used must comply
with the specifications of EC Directive 89/686/EEC and the related standard EN374. Wear
protective gloves.
Skin and body protection Long sleeved clothing. Chemical resistant apron. Wear suitable protective clothing.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations Wash hands before breaks and immediately after handling the product. Remove and wash
contaminated clothing and gloves, including the inside, before re-use. Regular cleaning of
equipment, work area and clothing is recommended. Avoid contact with skin, eyes or
clothing. Do not eat, drink or smoke when using this product. Wash hands before breaks
and after work. Wear suitable gloves and eye/face protection. Do not breathe dust. Take off
contaminated clothing and wash it before reuse. Contaminated work clothing should not be
allowed out of the workplace.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.

PHYSICAL AND CHEMICAL PROPERTIES9.1. Information on basic physical and chemical properties
Physical state Solid
Appearance Solid
Colour off-white
Odour No information available.
Odour threshold No information available
Property Values
Melting point / freezing point > 227 °C
Initial boiling point and boiling
range
No data available
Flammability No data available
Flammability Limit in Air
Upper flammability or explosive
limits
No data available
Lower flammability or explosive
limits
No data available
Flash point No data available
Autoignition temperature No data available
Decomposition temperature
pH No data available
pH (as aqueous solution) No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
Water solubility No data available
Solubility(ies) slightly soluble, Ethyl acetate
Partition coefficient No data available
Vapour pressure No data available
Relative density No data available
Bulk density No data available
Liquid Density No data available
Relative vapour density No data available
Particle characteristics
Particle Size No information available
Particle Size Distribution No information available
9.2. Other information
Molecular weight 380.91
Molecular formula C12 H8 Cl6 O
9.2.1. Information with regards to physical hazard classes
Not applicable
9.2.2. Other safety characteristics
No information available
STABILITY AND REACTIVITY10.1. Reactivity
Reactivity No information available.
10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data
Sensitivity to mechanical impact None.
Sensitivity to static discharge None.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.
10.4. Conditions to avoid
Conditions to avoid Excessive heat.
10.5. Incompatible materials
Incompatible materials None known based on information supplied.
Hazardous decomposition products None known based on information supplied.
TOXICOLOGICAL INFORMATION11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Information on likely routes of exposure
Product Information
Inhalation Specific test data for the substance or mixture is not available. Toxic by inhalation. (based
on components).
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available. Toxic in contact with skin.
(based on components).
Ingestion Specific test data for the substance or mixture is not available. Fatal if swallowed. (based on
components).
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Coughing and/ or wheezing. Difficulty in breathing.
Numerical measures of toxicity
Acute toxicity
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/eye irritation No information available.
Respiratory or skin sensitisation No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Aspiration hazard No information available.
11.2. Information on other hazards
11.2.1. Endocrine disrupting properties
Endocrine disrupting properties No information available.
11.2.2. Other information
Other adverse effects No information available.

ECOLOGICAL INFORMATION12.1. Toxicity
Ecotoxicity Very toxic to aquatic life with long lasting effects.
12.2. Persistence and degradability
Persistence and degradability No information available.
12.3. Bioaccumulative potential
Bioaccumulation No information available.
12.4. Mobility in soil
Mobility in soil No information available.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment The product does not contain any substance(s) classified as PBT or vPvB.
12.6. Endocrine disrupting properties
Endocrine disrupting properties No information available.
12.7. Other adverse effects
No information available.
DISPOSAL CONSIDERATIONS13.1. Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
TRANSPORT INFORMATIONIATA
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Endrin Ketone)
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN2811, Toxic solid, organic, n.o.s. (Endrin Ketone), 6.1, II
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions A3, A5
ERG Code 6L
IMDG
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Endrin Ketone)
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN2811, Toxic solid, organic, n.o.s. (Endrin Ketone), 6.1, II, Marine pollutant
14.5 Marine pollutant P
Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274
EmS-No F-A, S-A No information available
14.7 Maritime transport in bulk
according to IMO instruments
No information available
RID
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Endrin Ketone)
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN2811, Toxic solid, organic, n.o.s. (Endrin Ketone), 6.1, II, Environmentally Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 614
Classification code T2
ADR
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Endrin Ketone)
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN2811, Toxic solid, organic, n.o.s. (Endrin Ketone), 6.1, II, (D/E), Environmentally
Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 614
Classification code T2
Tunnel restriction code (D/E)
REGULATORY INFORMATION15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Water hazard class (WGK) strongly hazardous to water (WGK 3)
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work.
Authorisations and/or restrictions on use:
This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This
product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
DIRECTIVE (EU) 2021/1187 on the marketing and use of explosives precursors
Not applicable
Persistent Organic Pollutants
Not applicable
Dangerous substance category per Seveso Directive (2012/18/EU)
H2 - ACUTE TOXIC
E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1
Ozone-depleting substances (ODS) regulation (EC) 1005/2009
Not applicable
15.2. Chemical safety assessment
Chemical Safety Report A Chemical Safety Assessment has been carried out for this substance


OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!