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Flocoumafen

Item number681272
CAS90035-08-8
FormulaC33H25F3O4
Molecular weight542,54 g/mol
Quantity 1x50mg
Storage conditions4 °C
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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate November 4, 2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Flocoumafen
Catalog No.:681272
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity - Oral Category 1 - (H300)
Acute toxicity - Dermal Category 1 - (H310)
Acute toxicity - Inhalation (Dusts/Mists) Category 1 - (H330)
Reproductive toxicity Category 1B - (H360D)
Specific target organ toxicity — repeated exposure Category 1 - (H372)
Acute aquatic toxicity Category 1 - (H400)
Chronic aquatic toxicity Category 1 - (H410)
Label elements
PictogramGHS06 skull
skull
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
Signal word
Danger
Hazard statements
H300 - Fatal if swallowed
H310 - Fatal in contact with skin
H330 - Fatal if inhaled
H360D - May damage the unborn child
H372 - Causes damage to organs through prolonged or repeated exposure
H410 - Very toxic to aquatic life with long lasting effects
Precautionary Statements - EU (§28, 1272/2008)
P201 - Obtain special instructions before use
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P262 - Do not get in eyes, on skin, or on clothing
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing
P310 - Immediately call a POISON CENTER or doctor
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
2.3. Other hazards
No information available.
This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
EC No (EU Index No) 421-960-0 (607-375-00-5)
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute Tox. 1 (H300)
Acute Tox. 1 (H310)
Acute Tox. 1 (H330)
Repr. 1B (H360D)
STOT RE 1 (H372)
Aquatic Acute 1 (H400)
Aquatic Chronic 1 (H410)
Specific concentration limit (SCL)
Repr. 1B :: C>=0.003%
STOT RE 1 :: C>=0.05%
STOT RE 2 :: 0.005%<=C<0.05%
M-Factor 10
M-Factor (long-term) 10
Acute Toxicity Estimate
If LD50/LC50 data is not available or does not correspond to the classification category, then the appropriate conversion value from CLP Annex I, Table 3.1.2, is used to calculate the acute toxicity estimate (ATEmix) for classifying a mixture based on its components
Oral LD50 mg/kg 0.25
Dermal LD50 mg/kg 3
Inhalation LC50 - 4 hour - dust/mist - mg/L No data available
Inhalation LC50 - 4 hour - vapour - mg/L No data available
Inhalation LC50 - 4 hour - gas - ppm No data available
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No. 1907/2006 (REACH), Article 59)
FormulaC33H25F3O4
Molecular Weight (g/mol)542.54
CAS-No.90035-08-8
FIRST AID MEASURES4.1. Description of first aid measures
General advice Immediate medical attention is required. Show this safety data sheet to the doctor in
attendance.
Inhalation If breathing has stopped, give artificial respiration. Get medical attention immediately.
Remove to fresh air. Do not breathe dust. Do not use mouth-to-mouth method if victim
ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device. If breathing is
difficult, (trained personnel should) give oxygen.
Eye contact Get immediate medical attention. Rinse immediately with plenty of water, also under the
eyelids, for at least 15 minutes. Keep eye wide open while rinsing.
Skin contact Get immediate medical attention. Wash off immediately with soap and plenty of water while
removing all contaminated clothes and shoes.
Ingestion Get immediate medical attention. Do NOT induce vomiting. Rinse mouth. Never give
anything by mouth to an unconscious person.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination. Do not breathe dust. Do not use
mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration
with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
medical device. Use personal protective equipment as required. See section 8 for more
information.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms Coughing and/ or wheezing. Difficulty in breathing.
4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors Treat symptomatically.
FIRE-FIGHTING MEASURES5.1. Extinguishing media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the chemical
No information available.
5.3. Advice for firefighters
Special protective equipment and precautions for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.
Use personal protection equipment.
ACCIDENTAL RELEASE MEASURES6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required. Evacuate personnel to safe areas. Avoid generation of
dust. Do not breathe dust. Keep people away from and upwind of spill/leak.
Other information Refer to protective measures listed in Sections 7 and 8.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental precautions
Environmental precautions Prevent further leakage or spillage if safe to do so. Should not be released into the
environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information.
HANDLING AND STORAGE7.1. Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Take off contaminated clothing and wash it before reuse. Do not breathe dust. Avoid generation of dust. In case of insufficient ventilation, wear suitable
respiratory equipment. Handle product only in closed system or provide appropriate exhaust
ventilation. Do not eat, drink or smoke when using this product. Remove contaminated
clothing and shoes.
General hygiene considerations Wash hands before breaks and immediately after handling the product. Remove and wash
contaminated clothing and gloves, including the inside, before re-use. Regular cleaning of
equipment, work area and clothing is recommended. Do not breathe dust. Take off
contaminated clothing and wash it before reuse. Contaminated work clothing should not be
allowed out of the workplace. Avoid contact with skin, eyes or clothing. Do not eat, drink or
smoke when using this product. Wash hands before breaks and after work. Wear suitable
gloves and eye/face protection.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Store locked up. Keep containers tightly closed in a dry, cool and well-ventilated place.
Keep out of the reach of children. Please refer to the manufacturers certificate for specific
storage and transport temperature conditions. Store only in the original receptacle unless
other advice is given on the CoA.
7.3. Specific end use(s)
Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1. Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits
Romania 5 mg/g Creatinine - urine (Fluorine) - end of shift
Derived No Effect Level (DNEL) No information available.
Predicted No Effect Concentration (PNEC) No information available.
8.2. Exposure controls
Personal protective equipment
Eye/face protection Avoid contact with eyes. Wear safety glasses with side shields (or goggles).
Hand protection Wear suitable gloves. Impervious gloves. The protective gloves to be used must comply
with the specifications of EC Directive 89/686/EEC and the related standard EN374.
Skin and body protection Impervious clothing. Long sleeved clothing. Chemical resistant apron. Wear suitable
protective clothing.
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
General hygiene considerations Wash hands before breaks and immediately after handling the product. Remove and wash
contaminated clothing and gloves, including the inside, before re-use. Regular cleaning of
equipment, work area and clothing is recommended. Do not breathe dust. Take off
contaminated clothing and wash it before reuse. Contaminated work clothing should not be
allowed out of the workplace. Avoid contact with skin, eyes or clothing. Do not eat, drink or
smoke when using this product. Wash hands before breaks and after work. Wear suitable
gloves and eye/face protection.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
PHYSICAL AND CHEMICAL PROPERTIES9.1. Information on basic physical and chemical properties
Physical state Solid
Appearance Crystalline powder
Colour white
Odour No information available.
Odour threshold No information available
Property Values Remarks • Method
Melting point / freezing point 181 - 191 °C None known
Initial boiling point and boiling rangeNo data available None known
Flammability No data available None known
Flammability Limit in Air None known
Upper flammability or explosive
limits
No data available
Lower flammability or explosive
limits
No data available
Flash point No data available None known
Autoignition temperature No data available None known
Decomposition temperature None known
pH No data available None known
pH (as aqueous solution) No data available No information available
Kinematic viscosity No data available None known
Dynamic viscosity No data available None known
Water solubility No data available 1.04 mg/L @ 20 °C
Solubility(ies) No data available None known
Partition coefficient No data available None known
Vapour pressure No data available None known
Relative density 1.23 None known
Bulk density No data available
Liquid Density No data available
Relative vapour density No data available None known
Particle characteristics
Particle Size No information available
Particle Size Distribution No information available
9.2. Other information
Molecular weight 542.55
Molecular formula C33 H25 F3 O4
9.2.1. Information with regards to physical hazard classes
Not applicable
9.2.2. Other safety characteristics
No information available
STABILITY AND REACTIVITY10.1. Reactivity
Reactivity No information available.
10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data
Sensitivity to mechanical impact None.
Sensitivity to static discharge None.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.
10.4. Conditions to avoid
Conditions to avoid Excessive heat.
10.5. Incompatible materials
Incompatible materials None known based on information supplied.
Hazardous decomposition products None known based on information supplied.
TOXICOLOGICAL INFORMATION11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Information on likely routes of exposure
Product Information
Inhalation Specific test data for the substance or mixture is not available. Fatal if inhaled. (based on
components).
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available. Fatal in contact with skin.
(based on components).
Ingestion Specific test data for the substance or mixture is not available. Fatal if swallowed. (based on
components).
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Coughing and/ or wheezing. Difficulty in breathing.
Numerical measures of toxicity
Acute toxicity
Oral LD50 = 250 μg/kg ( Rat )
Dermal LD50 <3 mg/kg ( Rat )
Inhalation LC50 -
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/eye irritation No information available.
Respiratory or skin sensitisation No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity Contains a known or suspected reproductive toxin. Classification based on data available
for ingredients. May damage fertility or the unborn child.
European Union Repr. 1B
STOT - single exposure No information available.
STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure.
H372 - Causes damage to the following organs through prolonged or repeated exposure: Blood.
Aspiration hazard No information available.
11.2. Information on other hazards
11.2.1. Endocrine disrupting properties
Endocrine disrupting properties No information available.
11.2.2. Other information
Other adverse effects No information available.
ECOLOGICAL INFORMATION12.1. Toxicity
Ecotoxicity Very toxic to aquatic life with long lasting effects.
Algae/aquatic plants -
Fish LC50: = 0.091 mg/L (96h, Oncorhynchus mykiss)
Toxicity to microorganisms -
Crustacea EC50: = 0.66 mg/L (48h, Daphnia magna)
12.2. Persistence and degradability
Persistence and degradability No information available.
12.3. Bioaccumulative potential
Bioaccumulation There is no data for this product.
Component Information
Partition coefficient 4.7
12.4. Mobility in soil
Mobility in soil No information available.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment No information available.
12.6. Endocrine disrupting properties
Endocrine disrupting properties No information available.
12.7. Other adverse effects
No information available.
DISPOSAL CONSIDERATIONS13.1. Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
TRANSPORT INFORMATIONIATA
14.1 UN number or ID number UN3027
14.2 UN proper shipping name Coumarin derivative pesticide, solid, toxic (flocoumafen)
14.3 Transport hazard class(es) 6.1
14.4 Packing group I
Description UN3027, Coumarin derivative pesticide, solid, toxic (flocoumafen), 6.1, I
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions A3, A5
ERG Code 6L
IMDG
14.1 UN number or ID number UN3027
14.2 UN proper shipping name Coumarin derivative pesticide, solid, toxic (flocoumafen)
14.3 Transport hazard class(es) 6.1
14.4 Packing group I
Description UN3027, Coumarin derivative pesticide, solid, toxic (flocoumafen), 6.1, I, Marine pollutant
14.5 Marine pollutant P
Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 61, 274
EmS-No. F-A, S-A No information available
14.7 Maritime transport in bulk
according to IMO instruments
No information available
RID
14.1 UN number or ID number UN3027
14.2 UN proper shipping name Coumarin derivative pesticide, solid, toxic (flocoumafen)
14.3 Transport hazard class(es) 6.1
14.4 Packing group I
Description UN3027, Coumarin derivative pesticide, solid, toxic (flocoumafen), 6.1, I, Environmentally
Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 61, 274, 648
Classification code T7
ADR
14.1 UN number or ID number UN3027
14.2 UN proper shipping name Coumarin derivative pesticide, solid, toxic (flocoumafen)
14.3 Transport hazard class(es) 6.1
14.4 Packing group I
Description UN3027, Coumarin derivative pesticide, solid, toxic (flocoumafen), 6.1, I, (C/E),
Environmentally Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 61, 274, 648
Classification code T7
Tunnel restriction code (C/E)
REGULATORY INFORMATION15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
Germany
Water hazard class (WGK) strongly hazardous to water (WGK 3)
TA Luft (German Air Pollution Control Regulation)
Netherlands
Netherlands - List of Carcinogens -
Netherlands - List of Carcinogens -
Netherlands - List of Reproductive Toxins Development Category 1B
Poland SDS created according to the following Polish regulation: Act of February 25, 2011 on
chemical substances and their mixtures (Journal of Laws of 2018, item 143, as
amended). Regulation (EC) No 1907/2006 of the European Parliament and of the
Council on the Registration, Evaluation, Authorization and Restriction of Chemicals
(REACH), establishing the European Chemicals Agency (EC) as amended. Regulation
(EC) No 1272/2008 of the European Parliament and of the Council of 16 December
2008 on classification, labeling and packaging of substances and mixtures, as
amended. Regulation of the Minister of Health of 10 August 2012 on the criteria and
method of classifying chemical substances and their mixtures (Journal of Laws of
2012, item 1018). Regulation of the Minister of Health of 20 April 2012 on labeling
packaging of hazardous substances and mixtures and some mixtures (Journal of
Laws of 2012, item 445). Regulation of the Minister of Family, Labor and Social Policy
of 12 June 2018 on the maximum allowable concentrations and intensities of factors
harmful to health in the work environment (Journal of Laws of 2018, item 1286).
Announcement of the Minister of Economy, Labor and Social Policy of August 28,
2003 on the publication of the unified text of the Ordinance of the Minister of Labor
and Social Policy on general health and safety at work regulations (Journal of Laws
of 2003, No. 169, item 1650) . Regulation of the Minister of Health of 30 December
2004 on occupational safety and health related to the presence of chemical agents in
the workplace (Journal of Laws of 2005, No. 11, item 86). Act of December 14, 2012 on
waste (Journal of Laws of 2013, item 21) Regulation of the Minister of Health of
December 30, 2004 on occupational health and safety related to the presence of
chemical agents in the workplace (Journal U. of 2005, No. 11, item 86). Waste Act of
December 14, 2012 (Journal of Laws of 2013, item 21). Act of 13 June 2013 on the
management of packaging and packaging waste, Journal of Laws 2013, item 888).
Government statement of September 24, 2002 - European Agreement on the
International Carriage of Dangerous Goods by Road (ADR) (Journal of Laws No. 194,
item 1629 and Journal of Laws of 2003, No. 207, item 2013 and 2014).
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work.
Authorisations and/or restrictions on use:
This product contains one or more substance(s) subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
DIRECTIVE (EU) 2021/1187 on the marketing and use of explosives precursors
Not applicable
Restricted substance per REACH Annex XVII: 30. 75.
Persistent Organic Pollutants
Not applicable
Dangerous substance category per Seveso Directive (2012/18/EU)
H1 - ACUTE TOXIC
E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1
Ozone-depleting substances (ODS) regulation (EC) 1005/2009
Not applicable
Biocidal Products Regulation (EU) No 528/2012 (BPR) Product-type 14: Rodenticides
International Inventories
TSCA Complies under research and development exemption or is regulated by a different
government agency.
DSL/NDSL Contact supplier for inventory compliance status
EINECS/ELINCS Contact supplier for inventory compliance status
ENCS Contact supplier for inventory compliance status
IECSC Contact supplier for inventory compliance status
KECL Contact supplier for inventory compliance status
PICCS Contact supplier for inventory compliance status
AIIC Contact supplier for inventory compliance status
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
15.2. Chemical safety assessment
Chemical Safety Report A Chemical Safety Assessment is not required for this substance
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!