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Silica Spherical 100Å/10µm - Diol

Diol-functionalised Silica
 

Item number693809
CAS7631-86-9
FormulaO2Si
Molecular weight60,08 g/mol
Quantity 1x500g
storage conditions20 °C
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Silica Spherical 100Å/10µm - Diol

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate September 26, 2025
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Silica Spherical 100Å/10µm - Diol
Catalog No.:693809
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATIONPhysical hazards - Based on available data, the classification criteria are not met
Health hazards - Based on available data, the classification criteria are not met
Environmental hazards - Based on avail
Label elements
Pictogram
In accordance with Annex XIII of the REACH Regulation, inorganic substances do not require assessment
This product does not contain any known or suspected endocrine disruptors
COMPOSITION/INFORMATION ON INGREDIENTS
FormulaO2Si
Molecular Weight (g/mol)60.08
CAS-No.7631-86-9
FIRST AID MEASURESEye Contact - Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Skin Contact - Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur.
Ingestion - Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur.
Inhalation - Remove to fresh air. Get medical attention immediately if symptoms occur.
Self-Protection of the First Aider - No special precautions required.
FIRE-FIGHTING MEASURES5.1. Extinguishing media
Suitable Extinguishing Media
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Extinguishing media which must not be used for safety reasons
No information available. 5.2. Special hazards arising from the substance or mixture
Non-combustible. None reasonably foreseeable. Hazardous Combustion Products
None under normal use conditions. 5.3. Advice for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) andfull
protective gear.
ACCIDENTAL RELEASE MEASURES6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment as required. Ensure adequate ventilation. Avoid dust formation.

6.2. Environmental precautions
Should not be released into the environment. See Section 12 for additional Ecological Information.

6.3. Methods and material for containment and cleaning up
Sweep up and shovel into suitable containers for disposal. Avoid dust
formation.

6.4. Reference to other sections
Refer to protective measures listed in Sections 8 and 13.
HANDLING AND STORAGE7.1. Precautions for safe handling
Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid contact with skin, eyes or clothing. Avoidingestion and inhalation. Avoid dust formation.

Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feedingstuffs. Donot eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, beforere-use. Wash hands before breaks and after work.

7.2. Conditions for safe storage, including any incompatibilities
Keep containers tightly closed in a dry, cool and well-ventilated place.
Technical Rules for Hazardous Substances (TRGS) 510 Class 13
Storage Class (LGK) (Germany).

7.3. Specific end use(s)
Use in laboratories.
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1. Control parameters
Exposure limits
List source(s): UK - EH40/2005 Work Exposure Limits, Fourth edition. Published 2020. IRE - 2021 Code of Practice for the Chemical Agents Regulations, Schedule 1. Published by the Health and Safety Authority

Component The United Kingdom European Union Ireland
Silica, amorphous STEL: 18 mg/m3 15 min TWA: 6 mg/m3 8 hr. total
STEL: 7.2 mg/m3 15 min inhalable dust
TWA: 6 mg/m3 8 hr TWA: 2.4 mg/m3 8 hr.
TWA: 2.4 mg/m3 8 hr respirable dust
STEL: 18 mg/m3 15 min
STEL: 7.2 mg/m3 15 min

Biological limit values
This product, as supplied, does not contain any hazardous materials with biological limits established by the region specificregulatory bodies

Derived No Effect Level (DNEL) / Derived Minimum Effect Level (DMEL) - Workers

Predicted No Effect Concentration (PNEC)
No information available.

8.2. Exposure controls
Engineering Measures
None under normal use conditions.

Personal protective equipment
Eye - Protection Wear safety glasses with side shields (or goggles) (European standard - EN166)
Hand Protection - Protective gloves

Glove material Breakthrough time Glove thickness EU standard Glove comments
Natural rubber > 480 minutes - Level 1 EN388 (minimum requirement)
Nitrile rubber
Neoprene
PVC

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Inspect gloves before use.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of thegloves. (Refer to manufacturer/supplier for information)

Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as thedangerof cuts, abrasion.
Remove gloves with care avoiding skin contamination.

Respiratory Protection - No protective equipment is needed under normal use conditions.

Large scale/emergency use - Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposurelimitsare exceeded or if irritation or other symptoms are experienced
Recommended Filter type: Particle filter

Small scale/Laboratory use - Maintain adequate ventilation
Environmental exposure controls - No information available.



PHYSICAL AND CHEMICAL PROPERTIES9.1. Information on basic physical and chemical properties

Physical State Solid
Appearance - White
Odor - Odorless
Odor Threshold - No data available
Melting Point/Range - No data available
Softening Point - No data available
Boiling Point/Range - No information available
Flammability (liquid) - Not applicable Solid
Flammability (solid,gas) - No information available
Explosion Limits - No data available
Flash Point - No information available Method - No information available
Autoignition Temperature - No data available
Decomposition Temperature - No data available
pH 5.5 - 8 10% aq.solution
Viscosity - Not applicable Solid
Water Solubility - Insoluble
Solubility in other solvents - No information available

Partition Coefficient (n-octanol/water)
Vapor Pressure - No data available
Density / Specific Gravity -No data available
Bulk Density - No data available
Vapor Density - Not applicable
Vapor Density - Not applicable Solid
Particle characteristics - No data available

9.2. Other information
Molecular Formula O2 Si
Molecular Weight 60.08
Evaporation Rate Not applicable - Solid



STABILITY AND REACTIVITY10.1. Reactivity - None known, based on information available
10.2. Chemical stability - Stable under normal conditions.
10.3. Possibility of hazardous reactions
Hazardous Polymerization - Hazardous polymerization does not occur.
Hazardous Reactions - None under normal processing.
10.4. Conditions to avoid
Avoid dust formation. Incompatible products.
10.5. Incompatible materials - Strong oxidizing agents.
10.6. Hazardous decomposition products - None under normal use conditions
TOXICOLOGICAL INFORMATION11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Product Information
(a) acute toxicity;
Oral - Based on available data, the classification criteria are not met
Dermal - Based on available data, the classification criteria are not met
Inhalation - Based on available data, the classification

Component LD50 Oral LD50 Dermal LC50 Inhalation
Silica, amorphous >5000 mg/kg ( Rat ) >2000 mg/kg ( Rabbit ) -

(b) skin corrosion/irritation; - Based on available data, the classification criteria are not met
(c) serious eye damage/irritation; - Based on available data, the classification criteria are not met
(d) respiratory or skin sensitization;
Respiratory - Based on available data, the classification criteria are not met
Skin - Based on available data, the classification criteria are not met
(e) germ cell mutagenicity; - Based on available data, the classification criteria are not met
(f) carcinogenicity; - Based on available data, the classification criteria are not met
(g) reproductive toxicity; - Based on available data, the classification criteria are not met
(h) STOT-single exposure; - Based on available data, the classification criteria are not met
(i) STOT-repeated exposure; - Based on available data, the classification criteria are not met
Target Organs None known.
(j) aspiration hazard; - Not applicable Solid
Other Adverse Effects - The toxicological properties have not been fully investigated.
Symptoms / effects,both acute and delayed - No information available
11.2. Information on other hazards
Endocrine Disrupting Properties - Assess endocrine disrupting properties for human health. This product does not containanyknown or suspected endocrine disruptors
ECOLOGICAL INFORMATION12.1. Toxicity
Ecotoxicity effects This product contains the following substance(s) which are hazardous for the environment.

Component Freshwater Fish Water Flea Freshwater Algae
Silica, amorphous LC50: 5000 mg/L/96 h EC50: 7600 mg/L/48h EC50: 440 mg/L/72h

12.2. Persistence and degradability
Persistence - Insoluble in water.
Degradability - Not relevant for inorganic substances.
12.3. Bioaccumulative potential - May have some potential to bioaccumulate
12.4. Mobility in soil -Spillage unlikely to penetrate soil Is not likely mobile in the environment due its lowwatersolubility.
12.5. Results of PBT and vPvB assessment - In accordance with Annex XIII of the REACH Regulation, inorganic substances do not require assessment.
12.6. Endocrine disrupting properties
Endocrine Disruptor Information - This product does not contain any known or suspected endocrine disruptors.
12.7. Other adverse effects
Persistent Organic Pollutant - This product does not contain any known or suspected substance
Ozone Depletion Potential - This product does not contain any known or suspected substance
DISPOSAL CONSIDERATIONS13.1. Waste treatment methods
Waste from Residues/Unused Products - Chemical waste generators must determine whether a discarded chemical is classifiedasahazardous waste. Consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.
Contaminated Packaging - Empty remaining contents. Dispose of in accordance with local regulations. Do not re-use empty containers.
European Waste Catalogue (EWC) - According to the European Waste Catalog, Waste Codes are not product specific, but
application specific.
Other Information - Waste codes should be assigned by the user based on the application for which the product was used.
TRANSPORT INFORMATIONIMDG/IMO - Not regulated
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group

ADR - Not regulated
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group

IATA - Not regulated
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group
14.5. Environmental hazards - No hazards identified
14.6. Special precautions for user - No special precautions required.
14.7. Maritime transport in bulk according to IMO instruments - Not applicable, packaged goods

REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture.
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No.1907/2006
Not listed

15.2 Chemical safety assessment
A chemical safety assessment has not been carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!